Abstract:
The addition of borate results in a greater conversion of aldose to ketose in alkali-catalyzed isomerizations. Borate appears to increase both the rate of formation and the maximum amount of ketose formed. The method of isomerization described may be adopted on a preparative scale, and would be especially useful when only small amounts of aldose are available or when identification of an aldose by isomerization to its ketose is desired.
Registro:
Documento: |
Artículo
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Título: | Effect of borate on the alkali-catalyzed isomerization of sugars |
Autor: | Mendicino, J.F. |
Filiación: | Instituto de Investigaciones Bioquimicas Fundacion Campomar, Facultad de Ciencias Exactas y Naturales, Obligado 2490, Buenos Aires, Argentina Department of Chemistry, Western Reserve University, Cleveland, OH, United States
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Idioma: |
Inglés
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Año: | 1960
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Volumen: | 82
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Número: | 18
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Página de inicio: | 4975
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Página de fin: | 4979
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Título revista: | Journal of the American Chemical Society
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ISSN: | 00027863
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v82_n18_p4975_Mendicino |
Citas:
---------- APA ----------
(1960)
. Effect of borate on the alkali-catalyzed isomerization of sugars. Journal of the American Chemical Society, 82(18), 4975-4979.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v82_n18_p4975_Mendicino [ ]
---------- CHICAGO ----------
Mendicino, J.F.
"Effect of borate on the alkali-catalyzed isomerization of sugars"
. Journal of the American Chemical Society 82, no. 18
(1960) : 4975-4979.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v82_n18_p4975_Mendicino [ ]
---------- MLA ----------
Mendicino, J.F.
"Effect of borate on the alkali-catalyzed isomerization of sugars"
. Journal of the American Chemical Society, vol. 82, no. 18, 1960, pp. 4975-4979.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v82_n18_p4975_Mendicino [ ]
---------- VANCOUVER ----------
Mendicino, J.F. Effect of borate on the alkali-catalyzed isomerization of sugars. 1960;82(18):4975-4979.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v82_n18_p4975_Mendicino [ ]