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Abstract:

(Figure Presented) A comparison of the electrochemical gating of molecular conduction by a redox [Os(bipyridine)(pyridine)Cl] complex tethered to Au(111) with two different metal-molecule junctions in a scanning tunneling microscope nanogap is presented. The same redox molecular structure was tethered by mercaptobenzoic acid or reduction of the aryldiazonium salt of p-aminobenzoic acid, resulting in a Au-S or Au-C bond, respectively. A two-step electron-transfer mechanism with vibrational relaxation of the redox molecule is apparent in each case. Copyright © 2009 American Chemical Society.

Registro:

Documento: Artículo
Título:Electrochemical scanning tunneling spectroscopy of redox-active molecules bound by Au-C bonds
Autor:Ricci, A.M.; Calvo, E.J.; Martin, S.; Nichols, R.J.
Filiación:INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Buenos Aires CP 1428, Argentina
Department of Chemistry, Centre for Nanoscale Science, University of Liverpool, Liverpool L69 7ZD, United Kingdom
Palabras clave:Aryldiazonium salts; Au(1 1 1 ); Bipyridines; Electrochemical gating; Electron transfer mechanisms; Molecular conduction; Nano-gap; P-aminobenzoic acid; Redox molecules; Redox-active; Scanning tunneling microscopes; Scanning tunneling spectroscopy; Vibrational relaxation; Acids; Amino acids; Aviation; Chlorine compounds; Osmium; Scanning tunneling microscopy; Spectroscopy; Wind tunnels; Molecules; copper; gold; nanotube; article; chemical bond; chemical structure; electrochemical scanning tunneling spectroscopy; electrochemistry; electron transport; molecule; oxidation reduction reaction; spectroscopy
Año:2010
Volumen:132
Número:8
Página de inicio:2494
Página de fin:2495
DOI: http://dx.doi.org/10.1021/ja907867b
Título revista:Journal of the American Chemical Society
Título revista abreviado:J. Am. Chem. Soc.
ISSN:00027863
CODEN:JACSA
CAS:copper, 15158-11-9, 7440-50-8; gold, 7440-57-5
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v132_n8_p2494_Ricci

Referencias:

  • Tao, N., (1996) J. Phys. Rev. Lett, 76, p. 4066
  • Albrechtri, T., Moth-Poulsen, K., Christensen, J.B., Guckian, A., Bjomholm, T., Vos, J.G., Ulstrup, (2006) J. Faraday Discuss, 151, p. 265
  • Kubatkin, S., Danilov, A., Hjort, M., Cornil, J., Brédas, J.-L., Stuhr-Hansen, N., Hedegård, P., Bjørnholm, T., (2003) Natuer, 425, p. 698
  • Reed, M.A., Zhou, C., Muller, C.J., Burgin, T.P., Tour, J.M., (1997) Science, 278, p. 252
  • Cui, X.D., Primak, A., Zarate, X., Tomfohr, J., Sankey, O.F., Moore, A.L., Moore, T.A., Lindsay, S.M., (2001) Science, 294, p. 571
  • Xu, B.Q., Tao, N.J., (2003) J. science, 301, p. 1221
  • McCreery, R.L., Viswanathan, U., Kalakodimi, R.P., Nowak, A.M., (2006) Faraday Discuss, 131, p. 33
  • Ranganathan, S., Steidel, I., Anariba, F., McCreery, R.L., (2001) Nano Lett, 1, p. 491
  • Tao, N., (2006) J. Nat. Nanotechnol, 1, p. 173
  • Chen, F., Huang, Z., Tao, N., (2007) Appl. Phys. Lett, 97, p. 162106
  • Kiguchi, M., Miura, S., Hara, K., Sawamura, M., Murakoshi, K., (2007) Appl. Elas. Lett, 91, p. 053110
  • Park, Y.S., Whalley, A.C., Kamenetska, M., Steigerwald, M.L., Hybertsen, M.S., Nuckolls, C., Venkataraman, L., (2007) J. Am. Chem. Soc, 129, p. 15768
  • Chen, F., Li, X., Hihath, J., Huang, Z., Tao, N., (2006) J. Am. Chem. Soc, 128, p. 15874
  • Haiss, W., Martin, S., Leary, E., van Zalinge, H., Higgins, S.J., Bouffier, L., Nichols, R.J., (2009) J.Phys. Chem. C, 113, p. 5823
  • Donhauser, Z.J., Mantooth, B.A., Kelly, K.F., Butnm, L.A., Monnell, J.D., Stapleton, J.J., Price, D.W., Weiss, P.S., (2001) Science, 292, p. 2303
  • Allongue, P., Delamar, M., Desbat, B., Fagebaume, O., Hitmi, R., Pinson, J., Saveant, J.-M., (1997) J.Am. Chem. Soc, 119, p. 201
  • Adenier, A., Bernard, M.-G., Chehimi, M.M., Cabet-Deliry, E., Desbat, B., Fagebaume, O., Pinson, J., Podvorica, F., (2001) J. Am. Chem. Soc, 123, p. 4541
  • Laforgue, A., Addou, T., Belanger, D., (2005) Langmuir, 21, p. 6855
  • Ricci, A., Bonazzola, C., Calvo, E., (2006) J. Phys. Chem.chem. Phys, 8, p. 4297
  • Strano, M.S., Dyke, C.A., Usrey, M.L., Barone, P.W., Allen, M.J., Shan, H., Kittrell, C., Smalley, R.E., (2003) Science, 301, p. 1519
  • Liu, G.Z., Liu, J.Q., Booking, T., Eggers, P.K., Gooding, J., (2005) J. Chem. Phys, 319, p. 136
  • Adenier, A., Cabet-Deliry, E., Chaussé, A., Griveau, S., Mercier, F., Pinson, J., Vautrin-Ul, C., (2005) Chem. Mater, 17, p. 491
  • Bernard, M.-C., Chaussé, A., Cabet-Deliry, E., Chehimi, M.M., Pinson, J., Podvorica, F., Vautrin-Ul, C., (2003) Chem. Mater, 15, p. 3450
  • Albrecht, T., Guckian, A., Ulstrup, J., Vos, J.G., (2005) Nano Lett, 5, p. 1451
  • Albrecht, T., Guckian, A., Ulstrup, J., Vos, J.G., (2005) IEEE Trans. Nanotechnol, 4, p. 430
  • Albrecht, T., Moth-Poulsen, K., Christensen, J.B., Hjelm, J., Bjslashømholm, T., Ulstrup, J., (2006) J. Am. Chem. Soc, 128, p. 6574
  • Kuznetsov, A.M., Ulstrup, J., (2000) J. Phys. Chem. A, 104, p. 11531
  • Zhang, J., Chi, Q., Kuznetsov, A.M., Hansen, A.G., Wackerbarth, H., Christensen, H.E.M., Andersen, J.E.T., Ulstrup, J., (2002) J. Chem. B, 106, p. 1131
  • Zhang, J., Chi, Q., Albrecht, T., Kuznetsov, A.M., Grubb, M., Hansen, A.G., Wackerbarth, H., Ulstrup, J., (2005) Electrochim. Acta, 50, p. 3143
  • Ricci, A., Rolli, C., Rothacher, S., Baraldo, L., Bonazzola, C., Calvo, E., Tognalli, N., Fainstein, A., (2007) J. Solid State Electrochem, 11, p. 1511
  • Albrecht, T., Guckian, A., Kuznetsov, A.M., Vos, J.G., Ulstrup, J., (2006) J. Am. Chem. Soc, 128, p. 17132
  • Pobelov, I.V., Li, Z., Wandlowski, T., (2008) J. Am. Chem. Soc, 130, p. 16045
  • Kuznetsov, A.M., Ulstrup, J., (2001) J. Physichem. A, 105, p. 7494
  • Zhang, J., Kuznetsov, A.M., Medvedev, I.G., Chi, Q., Albrecht, T., Jensen, P.S., Ulstrup, J., (2008) chem. Rev, 108, p. 2737

Citas:

---------- APA ----------
Ricci, A.M., Calvo, E.J., Martin, S. & Nichols, R.J. (2010) . Electrochemical scanning tunneling spectroscopy of redox-active molecules bound by Au-C bonds. Journal of the American Chemical Society, 132(8), 2494-2495.
http://dx.doi.org/10.1021/ja907867b
---------- CHICAGO ----------
Ricci, A.M., Calvo, E.J., Martin, S., Nichols, R.J. "Electrochemical scanning tunneling spectroscopy of redox-active molecules bound by Au-C bonds" . Journal of the American Chemical Society 132, no. 8 (2010) : 2494-2495.
http://dx.doi.org/10.1021/ja907867b
---------- MLA ----------
Ricci, A.M., Calvo, E.J., Martin, S., Nichols, R.J. "Electrochemical scanning tunneling spectroscopy of redox-active molecules bound by Au-C bonds" . Journal of the American Chemical Society, vol. 132, no. 8, 2010, pp. 2494-2495.
http://dx.doi.org/10.1021/ja907867b
---------- VANCOUVER ----------
Ricci, A.M., Calvo, E.J., Martin, S., Nichols, R.J. Electrochemical scanning tunneling spectroscopy of redox-active molecules bound by Au-C bonds. J. Am. Chem. Soc. 2010;132(8):2494-2495.
http://dx.doi.org/10.1021/ja907867b