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Abstract:

The inorganic nitrosyl (NO+) complexes [Fe(CN) 5NO]2-, [Ru(bpy)2 (NO)Cl]2+, and [IrCl5(NO)]- are useful reagents for the nitrosation of a variety of organic compounds, ranging from amines to the relatively inert alkenes. Regarding [IrCl5(NO)]-, its high electrophilicity and inertness define it as a unique reagent and provide a powerful synthetic route for the isolation and stabilization of coordinated nitroso compounds that are unstable in free form, such as S-nitrosothiols and primary nitrosamines. Related to the high electrophilicity of [IrCl5(NO)]-, an unusual behavior is described for its PPh4+ salt in the solid state, showing an electronic distribution represented by Ir IV-NO• instead of IrIII-NO+ (as for the K+ and Na+ salts). © 2007 American Chemical Society.

Registro:

Documento: Artículo
Título:Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes
Autor:Doctorovich, F.; Di Salvo, F.
Filiación:Departamento de Química Inorgánica, Analítica Y Química Física, Pabellón II, C1428EHA Buenos Aires, Argentina
Palabras clave:inorganic compound; nitroso derivative; organic compound; article; chemical structure; chemistry; X ray crystallography; Crystallography, X-Ray; Inorganic Chemicals; Models, Molecular; Nitroso Compounds; Organic Chemicals
Año:2007
Volumen:40
Número:10
Página de inicio:985
Página de fin:993
DOI: http://dx.doi.org/10.1021/ar6000457
Título revista:Accounts of Chemical Research
Título revista abreviado:Acc. Chem. Res.
ISSN:00014842
CODEN:ACHRE
CAS:Inorganic Chemicals; Nitroso Compounds; Organic Chemicals
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00014842_v40_n10_p985_Doctorovich

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Citas:

---------- APA ----------
Doctorovich, F. & Di Salvo, F. (2007) . Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes. Accounts of Chemical Research, 40(10), 985-993.
http://dx.doi.org/10.1021/ar6000457
---------- CHICAGO ----------
Doctorovich, F., Di Salvo, F. "Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes" . Accounts of Chemical Research 40, no. 10 (2007) : 985-993.
http://dx.doi.org/10.1021/ar6000457
---------- MLA ----------
Doctorovich, F., Di Salvo, F. "Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes" . Accounts of Chemical Research, vol. 40, no. 10, 2007, pp. 985-993.
http://dx.doi.org/10.1021/ar6000457
---------- VANCOUVER ----------
Doctorovich, F., Di Salvo, F. Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes. Acc. Chem. Res. 2007;40(10):985-993.
http://dx.doi.org/10.1021/ar6000457