Abstract:
Dynamics of adsorption and viscoelasticity of biopolymers (β-lactoglobulin (β-lg) + polysaccharides (PS)) at 20°C and pH 7 have been studied. Protein concentration in the 'bulk phase was 0.1 wt%, and the concentration of polysaccharides (xanthan gum, λ-carrageenan, and propylenglicol alginate with different degrees of esterification and viscosity) was varied from 0.1% to 0.5 wt%. The results reveal a significant effect of surface-active and non surface-active polysaccharides on the dynamics of the formation and viscoelasticity of adsorbed films at the air-water interface. The rate of diffusion of the biopolymers increased in the mixed systems, but the effect was more significant at the highest concentration of polysaccharide (0.5 wt %). The rate of rearrangement of the adsorbed films decreased in the presence of polysaccharides as compared to the protein film. Competitive adsorption, complexation and limited thermodynamic incompatibility between β-lactoglobulin and polysaccharide would explain the observed effects. © 2006 American Institute of Chemical Engineers.
Registro:
Documento: |
Artículo
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Título: | Adsorption and rheological properties of biopolymers at the air-water interface |
Autor: | Baeza, R.; Pilosof, A.M.R.; Sanchez, C.C.; Rodríguez Patino, J.M. |
Filiación: | Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, (1428), Buenos Aires, Argentina Departamento de Ingeniería Química, Facultad de Química, Universidad de Sevilla, c/. Prof. Garcia Gonzalez, 1, 41012, Sevilla, Spain
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Palabras clave: | β-lactoglobulin; Adsorption; Air-water interface; Biopolymers; Interfacial activity; Macromolecules; Polysaccharides; Surface rheology; Adsorption; Interfaces (materials); Macromolecules; Polysaccharides; Rheology; Viscosity; Air-water interface; Interfacial activity; Lactoglobulin; Surface rheology; Biopolymers; Adsorption; Biopolymers; Interfaces (materials); Macromolecules; Polysaccharides; Rheology; Viscosity |
Año: | 2006
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Volumen: | 52
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Número: | 7
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Página de inicio: | 2627
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Página de fin: | 2638
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DOI: |
http://dx.doi.org/10.1002/aic.10855 |
Título revista: | AIChE Journal
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Título revista abreviado: | AIChE J.
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ISSN: | 00011541
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CODEN: | AICEA
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00011541_v52_n7_p2627_Baeza |
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Citas:
---------- APA ----------
Baeza, R., Pilosof, A.M.R., Sanchez, C.C. & Rodríguez Patino, J.M.
(2006)
. Adsorption and rheological properties of biopolymers at the air-water interface. AIChE Journal, 52(7), 2627-2638.
http://dx.doi.org/10.1002/aic.10855---------- CHICAGO ----------
Baeza, R., Pilosof, A.M.R., Sanchez, C.C., Rodríguez Patino, J.M.
"Adsorption and rheological properties of biopolymers at the air-water interface"
. AIChE Journal 52, no. 7
(2006) : 2627-2638.
http://dx.doi.org/10.1002/aic.10855---------- MLA ----------
Baeza, R., Pilosof, A.M.R., Sanchez, C.C., Rodríguez Patino, J.M.
"Adsorption and rheological properties of biopolymers at the air-water interface"
. AIChE Journal, vol. 52, no. 7, 2006, pp. 2627-2638.
http://dx.doi.org/10.1002/aic.10855---------- VANCOUVER ----------
Baeza, R., Pilosof, A.M.R., Sanchez, C.C., Rodríguez Patino, J.M. Adsorption and rheological properties of biopolymers at the air-water interface. AIChE J. 2006;52(7):2627-2638.
http://dx.doi.org/10.1002/aic.10855