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Abstract:

Cassava (Manihot esculenta) bagasse is a fibrous by-product generated in the tuber processing. After washing and peeling, the cassava is grated and then water is added in order to extract the starch. The mixture is filtered such that a rich starch solution and a wet solid residue can be separated. This slurry, known as bagasse, comprises up to 20% of the weight of the processed cassava. In addition, as the extraction of starch from cassava is less efficient than those based on processing of potato or maize, the bagasse contains around 50-70% of starch on a dry basis. As it has no important use, with the exception of animal feed, the bagasse is usually rejected to water courses increasing the environmental pollution. Therefore, several strategies are being studied to find useful applications for this by-product. Pyrolysis of the bagasse and copyrolysis, namely the thermal degradation of mixtures of the bagasse and lignocellulosic biomass in inert atmosphere, could be an appealing possibility to employ this waste in order to generate green energy and/or other value-added products. In particular, growing attention is paid to the liquid products arising from pyrolysis/copyrolysis, commonly known as bio-oils, since they show many of the advantages of liquid fuels, such as inexpensive storage and transportation, and high energy density. In this scenario, the processes of pyrolysis of cassava starch, the major constituent of dry cassava bagasse, and of copyrolyisis of the starch with peanut hulls, an abundant lignocellulosic residue, were studied by performing experiments in a fixed-bed reactor at different process temperatures (400ºC – 600ºC). The pyrolysis of the starch led to a higher maximum yield of bio-oils that took place at a lower temperature than the copyrolysis (57 wt% at 400ºC vs. 49 wt% at 500ºC). Physichochemical characterization of the three kinds of pyrolysis/copyrolysis products with emphasis on the bio-oils was carried out mainly by proximate and ultimate analyses, Karl-Fischer titration, Fourier-transformed infrared spectroscopy, N2 adsorption, scanning electronic microscopy, and gas chromatography (GC-TCD and GC-MS). While the pyrolysis of the starch resulted in bio-oils with less nitrogen content, the copyrolysis produced bio-oils with lower content of oxygen and higher carbon percent. Water content of the bio-oils increased with rising process temperatures and it was lower for the liquids resulting from the pyrolysis of the starch. Also, the bio-oils arising from the pyrolysis of the starch presented more sugar compounds and fewer phenols. Besides, the pyrolysis of the starch led to a lower yield of solid products (bio-chars) than the copyrolysis. They showed greater high heating values (up to 35 MJ/kg) than those arising from the latter process in agreement with their larger carbon content and lower presence of ash. In addition, the bio-chars produced at the highest process temperature presented an incipient pore development, suggesting their possible use as rough adsorbents or as intermediary for further upgrading to activated carbons. Furthermore, the pyrolysis of cassava starch and copyrolysis with peanut hulls generated gases, principally CO2, CO, CH4 and H2, that could help to sustain the processes. © 2017 by Nova Science Publishers, Inc.

Registro:

Documento: Parte de libro
Título:Potential uses of cassava bagasse for bioenergy generation by pyrolysis and copyrolysis with a lignocellulosic waste
Autor:Gurevich Messina, L.I.; Bonelli, P.R.; Cukierman, A.L.
Filiación:Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Depto. de Industrias, Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía (PINMATE), Ciudad Universitaria., Buenos Aires, Argentina
Universidad de Buenos Aires, Facultad de Farmacia y Bioquímica, Depto. de Tecnología Farmacéutica, Cátedra de Tecnología Farmacéutica II., Buenos Aires, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires, Argentina
Palabras clave:Bio-oils; Bioenergy; Cassava bagasse; Cassava starch; Copyrolysis; Pyrolysis
Año:2017
Página de inicio:335
Página de fin:356
Título revista:Handbook on Cassava: Production, Potential Uses and Recent Advances
Título revista abreviado:Handb. on Cassava: Production, Potential Uses and Recent Advances
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97815361_v_n_p335_GurevichMessina

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Citas:

---------- APA ----------
Gurevich Messina, L.I., Bonelli, P.R. & Cukierman, A.L. (2017) . Potential uses of cassava bagasse for bioenergy generation by pyrolysis and copyrolysis with a lignocellulosic waste. Handbook on Cassava: Production, Potential Uses and Recent Advances, 335-356.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97815361_v_n_p335_GurevichMessina [ ]
---------- CHICAGO ----------
Gurevich Messina, L.I., Bonelli, P.R., Cukierman, A.L. "Potential uses of cassava bagasse for bioenergy generation by pyrolysis and copyrolysis with a lignocellulosic waste" . Handbook on Cassava: Production, Potential Uses and Recent Advances (2017) : 335-356.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97815361_v_n_p335_GurevichMessina [ ]
---------- MLA ----------
Gurevich Messina, L.I., Bonelli, P.R., Cukierman, A.L. "Potential uses of cassava bagasse for bioenergy generation by pyrolysis and copyrolysis with a lignocellulosic waste" . Handbook on Cassava: Production, Potential Uses and Recent Advances, 2017, pp. 335-356.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97815361_v_n_p335_GurevichMessina [ ]
---------- VANCOUVER ----------
Gurevich Messina, L.I., Bonelli, P.R., Cukierman, A.L. Potential uses of cassava bagasse for bioenergy generation by pyrolysis and copyrolysis with a lignocellulosic waste. Handb. on Cassava: Production, Potential Uses and Recent Advances. 2017:335-356.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97815361_v_n_p335_GurevichMessina [ ]