Abstract:
The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography.
Registro:
| Documento: |
Artículo
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| Título: | Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate |
| Autor: | Perec, M.; Baggio, R.; Garland, M.T. |
| Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Buenos Aires, Argentina
Departamento de Física, Comisión National de Energía Atómica, Buenos Aires, Argentina
Departamento de Física, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Casilla 487-3, Santiago de Chile, Chile
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| Año: | 1999
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| Volumen: | 55
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| Número: | 6
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| Página de inicio: | 858
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| Página de fin: | 860
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| DOI: |
http://dx.doi.org/10.1107/S0108270199001420 |
| Título revista: | Acta Crystallographica Section C: Crystal Structure Communications
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| Título revista abreviado: | Acta Crystallogr Sect C Cryst Struct Commun
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| ISSN: | 01082701
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| CODEN: | ACSCE
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| PDF: | https://bibliotecadigital.exactas.uba.ar/download/paper/paper_01082701_v55_n6_p858_Perec.pdf |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v55_n6_p858_Perec |
Referencias:
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- Sheldrick, G.M., (1994) SHELXTL/PC. Version 5.0, , Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA
- Sheldrick, G.M., (1997) SHELXL97. Program for the Refinement of Crystal Structures, , University of Göttingen, Germany
- (1991) P3/P4-PC Diffractometer Program. Version 4.27, , Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA
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Citas:
---------- APA ----------
Perec, M., Baggio, R. & Garland, M.T.
(1999)
. Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate. Acta Crystallographica Section C: Crystal Structure Communications, 55(6), 858-860.
http://dx.doi.org/10.1107/S0108270199001420---------- CHICAGO ----------
Perec, M., Baggio, R., Garland, M.T.
"Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate"
. Acta Crystallographica Section C: Crystal Structure Communications 55, no. 6
(1999) : 858-860.
http://dx.doi.org/10.1107/S0108270199001420---------- MLA ----------
Perec, M., Baggio, R., Garland, M.T.
"Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate"
. Acta Crystallographica Section C: Crystal Structure Communications, vol. 55, no. 6, 1999, pp. 858-860.
http://dx.doi.org/10.1107/S0108270199001420---------- VANCOUVER ----------
Perec, M., Baggio, R., Garland, M.T. Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate. Acta Crystallogr Sect C Cryst Struct Commun. 1999;55(6):858-860.
http://dx.doi.org/10.1107/S0108270199001420