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Pieslinger, G.E.; Albores, P.; Slep, L.D.; Baraldo, L.M. "Class III delocalization in a cyanide-bridged trimetallic mixed-valence complex" (2014) Angewandte Chemie - International Edition. 53(5):1293-1296
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Abstract:

The NIR and IR spectroscopic properties of the cyanide-bridged complex, trans-[Ru(dmap)4{(m-CN)Ru- (py)4Cl}2]3+ (py=pyridine, dmap=4- dimethylaminopyridine) provide strong evidence that this trimetallic ion behaves as a Class III mixed-valence species, the first example reported of a cyanide-bridged system. This has been accomplished by tuning the energy of the fragments in the trimetallic complex to compensate for the intrinsic asymmetry of the cyanide bridge. Moreover, (TD)DFT calculations accurately predict the spectra of the trans-[Ru(dmap)4{(m-CN)Ru(py)4Cl}2]3+ ion and confirms its delocalized nature. © 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Registro:

Documento: Artículo
Título:Class III delocalization in a cyanide-bridged trimetallic mixed-valence complex
Autor:Pieslinger, G.E.; Albores, P.; Slep, L.D.; Baraldo, L.M.
Filiación:Departamento de Quimica Inorginica, Analatica y Quimica Fisica, Universidad de Buenos Aires, Pabellon 2, 38 piso Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina
Palabras clave:Cyanometalates; Density functional calculations; Metal-metal interactions; Mixed-valence compounds; Ruthenium
Año:2014
Volumen:53
Número:5
Página de inicio:1293
Página de fin:1296
DOI: http://dx.doi.org/10.1002/anie.201307025
Título revista:Angewandte Chemie - International Edition
Título revista abreviado:Angew. Chem. Int. Ed.
ISSN:14337851
CODEN:ACIEF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v53_n5_p1293_Pieslinger

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Citas:

---------- APA ----------
Pieslinger, G.E., Albores, P., Slep, L.D. & Baraldo, L.M. (2014) . Class III delocalization in a cyanide-bridged trimetallic mixed-valence complex. Angewandte Chemie - International Edition, 53(5), 1293-1296.
http://dx.doi.org/10.1002/anie.201307025
---------- CHICAGO ----------
Pieslinger, G.E., Albores, P., Slep, L.D., Baraldo, L.M. "Class III delocalization in a cyanide-bridged trimetallic mixed-valence complex" . Angewandte Chemie - International Edition 53, no. 5 (2014) : 1293-1296.
http://dx.doi.org/10.1002/anie.201307025
---------- MLA ----------
Pieslinger, G.E., Albores, P., Slep, L.D., Baraldo, L.M. "Class III delocalization in a cyanide-bridged trimetallic mixed-valence complex" . Angewandte Chemie - International Edition, vol. 53, no. 5, 2014, pp. 1293-1296.
http://dx.doi.org/10.1002/anie.201307025
---------- VANCOUVER ----------
Pieslinger, G.E., Albores, P., Slep, L.D., Baraldo, L.M. Class III delocalization in a cyanide-bridged trimetallic mixed-valence complex. Angew. Chem. Int. Ed. 2014;53(5):1293-1296.
http://dx.doi.org/10.1002/anie.201307025