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Abstract:

The reaction of methanolic ammonia with the hexa-O-acetyl and hexa-O-benzoyl derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose affords the 1,1-bis(acylamido)-1-deoxy-D-heptitols (2,3), from which the acetates have been prepared. The yields of 2 and 3 are in general higher than those of the corresponding hexose derivatives. On ammonolysis of hexa-O-benzoyl-D-glycero-L-manno-heptose, an N-benzoyl-D-glycero-L-manno-heptosylamine is formed, together with the main product. © 1967.

Registro:

Documento: Artículo
Título:Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose
Autor:Deferrari, J.O.; de Lederkremer, R.M.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Perú, 222 Buenos Aires, Argentina
Año:1967
Volumen:4
Número:5
Página de inicio:365
Página de fin:370
DOI: http://dx.doi.org/10.1016/S0008-6215(00)80193-7
Título revista:Carbohydrate Research
Título revista abreviado:Carbohydr. Res.
ISSN:00086215
CODEN:CRBRA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v4_n5_p365_Deferrari

Citas:

---------- APA ----------
Deferrari, J.O. & de Lederkremer, R.M. (1967) . Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose. Carbohydrate Research, 4(5), 365-370.
http://dx.doi.org/10.1016/S0008-6215(00)80193-7
---------- CHICAGO ----------
Deferrari, J.O., de Lederkremer, R.M. "Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose" . Carbohydrate Research 4, no. 5 (1967) : 365-370.
http://dx.doi.org/10.1016/S0008-6215(00)80193-7
---------- MLA ----------
Deferrari, J.O., de Lederkremer, R.M. "Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose" . Carbohydrate Research, vol. 4, no. 5, 1967, pp. 365-370.
http://dx.doi.org/10.1016/S0008-6215(00)80193-7
---------- VANCOUVER ----------
Deferrari, J.O., de Lederkremer, R.M. Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose. Carbohydr. Res. 1967;4(5):365-370.
http://dx.doi.org/10.1016/S0008-6215(00)80193-7